Filling with aluminum you still get heat soak.
If you want to prevent the paint from burning, do the same what folks do with the exhaust ports, paint first with some Eastwood exhaust paint or other similar product, before you lay down the color.
https://www.eastwood.com/paints/hi-t...st-paints.html
Pretty sure the POR-15 high heat paint is the same thing:
https://www.por15.com/POR-15-High-Temp_p_104.html
It's always best to etch before you paint, but you don't have to, just lasts longer if you do. Use a good quality engine paint too, I like Dupli-color ceramic.
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1970 GTO Judge Tribute Pro-Tour Project 535 IA2
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1971 Trans Am 463, 315cfm E-head Sniper XFlow EFI, TKO600 extreme, 9", GW suspension, Baer brakes, pro tour car
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